newman projection वाक्य
उदाहरण वाक्य
मोबाइल
- The structure is shown in Newman projection.
- The Newman projection and the sawhorse projection are used to depict specific conformers or to distinguish oblique vantage point.
- If one looks down the axis of the C C bond, one will see the so-called Newman projection.
- Determining the axial stereochemistry of biaryl atropisomers can be accomplished through the use of a Newman projection along the axis of hindered rotation.
- Fischer projections should not be confused with Lewis structures, which do not contain any information about three dimensional Newman projections are normally used to represent the stereochemistry of alkanes.
- In newman projection it can be seen how the steric bulks of chromium groups and the steric bulks of the alkyl and halogen groups drive this reaction towards anti elimination.
- In the Newman projection, a circle is used to represent a plane perpendicular to the bond, distinguishing the substituents on the front carbon from the substituents on the back carbon.
- This Newman projection illustrates the Cornforth and Felkin transition state that places the EWG " anti-" to the incoming nucleophile, regardless of its steric bulk relative to R S and R L.
- For some molecules such as those of " n "-butane, there can be special versions of staggered conformations called " gauche " and " anti "; see first Newman projection diagram in Conformational isomerism.
- A "'Newman projection "', useful in alkane stereochemistry, visualizes chemical conformations of a carbon-carbon chemical bond from front to back, with the front carbon represented by a dot and the back carbon as a circle ( see below ).
- In the example of staggered ethane in Newman projection, a hydrogen atom on one carbon atom has a 60?"'torsional angle "'or "'torsion angle "'with respect to the nearest hydrogen atom on the other carbon so that steric hindrance is minimised.
- The preference for the formation of the threo isomer can be explained by the rule stated above by having the active nucleophile in this reaction attacking the carbonyl group from the least hindered side ( see Newman projection "'A "') when the carbonyl is positioned in a gauche orientation and phenyl as the most bulky group in the anti conformation.
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